Great Picture
I saw roughly the same in the midwest at about 9PM. The shuttle appeared to be 2-3 degrees ahead of the station and maybe half a degree lower in the sky. Both were about 20 degrees off the horizon and very hard to see over the city lights. In fact, I think I would have missed it entirely if I didn't catch a very bright reflection that lasted less than a second... I can only guess that the reflection came off the Station's solar panels. For a breif instant it was brighter than the planet Venus (which was in the same vicinity of sky).
It was a great night for looking up!
Scott