Sodium? oh you mean this image.....

THis one...?
With plutonium of all elements? This can't be geological, uh DUH. RTG's ok. :) Zr must be a decay byproduct....
The thing about the alkali metals (Na, and K in this case) is their peaks are superimposed on the bremstralung signal so the relative intensity of these along with the sodium peak is over represented.
As usual, HyperPhysics goves a pretty good explanation of what's going on:
http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/xrayc.html#c1
