Mercury
One of the interesting things about Mercury's orbit is that is is extremely oblate (elliptical). This allowed Einstein to base a fundamental test of Relativity on the evolution of Mercury's orbit - it's precession.
It also means that the tidal effects on Mercury conspire to produce a near-synchronicity of its orbital rate and rotation rate WHEN IT IS CLOSER TO THE SUN.
Tidal effects vary as 1/R^3, so it is in the closest parts of the orbit that tides are strongest.
Note that this implies a very long-term stability of the oblateness of mercury's orbit.
